BRIOTECH HOCL

BRIOTECH, ITS LOGOS, LANGUAGE, AND IMAGES ARE TRADEMARKS AND/OR THE COPYRIGHT PROPERTY OF BRIOTECH, INC. AND/OR ITS AFFILIATES. © 2013-2018

MATERIAL SAFETY DATA SHEET

Date Issued: 04.01.2017   Revision: 2.0 By: BRIOTECH
BRIOTECH, INC. assumes no legal responsibility for application or reliance on the data provided in this document. The information is provided in good faith and without warranty. All risks are assumed by the product user.
1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name: BRIOTECH HOCL Synonym: HOCl, Cl HO, Hypochlorous Acid, Electrolyzed Water, Electro-chlorinated Water, Dilute Aqueous Saline Solution Company Information:     Comment: To the best of our knowledge, this Material Safety Data Sheet is in compliance with US OSHA 29 CFR 1910.1200, 91/155/EEC as well as the Canadian Hazardous Products Act. 2. COMPOSITION OF BRIOTECH HOCL Electro-chlorinated Water: a. CAS Registry – Chemical Abstract Service Registration Number b. EINECS – European Inventory of Existing Chemical Substances c. RTECS – Registry of Toxic Effects of Chemical Substances d. TSCA – Toxic Substance Control Act 3. HAZARDOUS IDENTIFICATION This product does not contain hazardous materials as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200; or as defined under SARA 311 and 312. Physical Appearance: Colorless, clear liquid Cautions: In sensitive individuals, may cause eye and skin irritations; may cause digestive tract irritation, nausea, vomiting and/or diarrhea. Risk by accidental inhalation are not known but considered minimal. 4. PURITY OF COMPOSITION: Using Molecular Analysis Raman Spectroscopy Presenting a single prominent point indicating no other species other than HOCl (UW Physical Sciences Laboratory 2015/2017).
BRIOTECH, INC. 19816 – 141st Place NE Woodinville, WA 98072
TEL:  425.488.4300          TOLL FREE:  888.900.6063 WEB:  www.briotechusa.com   |   http://briotechinternational.com EMAIL:  info@briotechusa.com          FAX:  425.398.9992
BRIOTECH, ITS LOGOS, LANGUAGE, AND IMAGES ARE TRADEMARKS AND/OR THE COPYRIGHT PROPERTY OF BRIOTECH, INC. AND/OR ITS AFFILIATES. © 2013-2018
Component Water         Sodium Chloride    Hypochlorous Acid
Wt % 99.08 % 0.90 % 0.02 %
aCAS Registry 7732-18-5 8028-77-1 7790-92-3
bEINECS 215-185-5 231-598-3 232-232-5
cRETECS ZC0110000 VZ4725000 NH3470000
dTSCA TSCA 8(b) TSCA 8(b) TSCA 8(b)
Wavenumbers (cm    )
-1
5. STABILITY OF COMPOSITION:  450 day half life 6. FIRST AID MEASURES This product is not known to cause any irritations by contact to the eyes, skin, through inhalation or ingestion; however, individuals may respond differently to various applications and in the interest of safety we elaborate on the previously mentioned cautions. This product is not for consumption; in an event of accidental exposure or overexposure through: Eye Contact: Safe for eyes; If irritation develops, check for and remove contact lenses if present. If irritation persists, rinse with cool, clean water. Skin Contact: Safe for skin contact; If irritation develops, wash with clean cool water. Ingestion: Safe for ingestion; however, as a saline product, can cause nausea if swallowed. If irritation develops, drink 2 to 4 cups of milk or water. Note that this is a topical product and not intended for consumption. Inhalation: Safe for inhalation: If irritation develops, remove from exposure to Briotech HOCl and into fresh air. 7. FIRE FIGHTING MEASURES This aqueous medium is not considered a fire hazard (non-flammable material). 8. ACCIDENTAL RELEASE MEASURES Minor spills may be mopped up and discarded in waste or sink. Major spills (industrial) should be cleaned up as you would for  salt water. No personal protective gear required; e.g., protective gloves, goggles, face shield, apron. The material is not hazardous and turns to normalized saline upon contact. 9. HANDLING AND STORAGE Industrial Handling: Keep containers tightly closed and away from UV.  Normal Handling: No special handling required. Storage: Store in a cool dry place away from direct sunlight and heat. Do not freeze. Minimum Temperature: 4°C Maximum Temperature: 70°C Optimum Temperature: 20°C to 25°C 10. PHYSICAL AND CHEMICAL PROPERTIES Physical State and Appearance: Clear, colorless liquid Odor: Very dilute chlorine or bleach Molecular Weight (g/mol): As a whole; N/A Chemistry: Individual Components:   Water – 18.02;   Sodium Chloride – 58.44;   Hypochlorous Acid – 52.46 pH: Produced between 3.9 and 6.5 Vapor Pressure (mm Hg): 760 Boiling Point: 101°C Freezing Point: May begin to freeze at -0.1°C with concomitant precipitation of sodium chloride Solubility: Water (complete) Specific Density (g/mL at 20 oC): 1.0 % Volatiles: None Flash Point: N/A 11. STABILITY AND REACTIVITY Conditions to Avoid: The material is considered safe under normal storage and handling conditions. Avoid high temperature, heat, sparks and flames. The medium is non-flammable. Chemical Stability: This product is uniquely stable and safe in closed containers stored cool and dark (away from direct sunlight and sources of heat). Hazardous Polymerization: Has not been reported and highly unlikely to occur. Hazardous Decomposition Products: Low concentrations of chlorine may evolve if heated. Incompatibilities: Ammonia, ammonium salts, reducing agents, reactive metals, iron and steel, aziridine, methanol, formic acid. 12. TOXICOLOGICAL INFORMATION No known hazards in normal use or exposure. Acute Dose Effects Eyes: Mild irritation Inhalation LC     : No data available for solution; decomposition as chlorine 293 ppm in 1 hour (rat); 137 ppm in 1 hour (mouse); note solutions are very dilute and the total amounts shown exceed that per liter of solution (rat). Dermal / Skin: Removes natural oils from skin causing dryness, prolonged exposure may result in irritation LD50 > 5000 mg/kg. Oral: LD50 3000 mg/kg (rat); 4000 mg/kg (mouse). Sensitization: N/A Carcinogenicity As Listed by IARC: None As Listed by NTP: None As Listed by OSHA: None As Listed by ACGIH: None As Listed by NIOSH: None Mutagenicity: N/A Reproductive Effects: N/A Teratogenic Effects: N/A 13. ECOLOGICAL INFORMATION Environmental Impact: This product is not expected to bio-accumulate. When released into the air or water, its projected half-life is estimated to be <1 to 10 days. Accidental spills in aquatic environments are to be avoided due to salt content; expect immediate oxidative dilution on occurrence. 14. DISPOSAL CONSIDERATION As a waste, this material in its raw form is not considered Hazardous Waste under RCA (29 CFR 261). Waste should be appropriately diluted and pH balanced to local water management standards with water and flushed to drain as local, state and federal ordinances allow and following proper waste stream management policies of the same and for the company. 15. TRANSPORTATION INFORMATION Product Label: BRIOTECH HOCL: Hypochlorous Acid/ Dilute Aqueous Saline Solution D.O.T. Shipping Name: Water, Saline Water Technical Shipping Name: Oxidized Water D.O.T. Hazard Class: None UN Number: None D.O.T. Label: None D.O.T. Placard: None Bulk Class: N/A Package Class: 70, PG III Canadian Transport and European Transport Information not available or known. 16. REGULATORY INFORMATION TSCA Chemical Inventory: All of the components in this product are listed on the TSCA Inventory. TSCA Sec 4 Chemical Test Rule: None of the components in this product are under a Chemical Test Rule. TSCA Sec 8(d): None of the components in this product are on the Health and Safety Reporting List. TSCA Sec 12(b) Notices of Export: None of the components in this product are on this list. TSCA Significant New Use Rule (SNUR): None of the components in this product are on this list. SARA Sec 302 (EHS) TPQ: None of the components in this product have a TPQ. SARA Sec 302 (EHS) RQ: None of the components in this product have a RQ. SARA Sec 311/312: NO; Chronic – NO; Fire – NO; Release of Pressure – NO; Reactivity – NO SARA 313 List: None of the product components are reportable under Section 313 Title III and 40 CFR Part 372. CERCLA Hazardous Substances and Corresponding RQs: N/A RCRA: None of the components in this product are on this list. Clean Air Act: Hazardous Air Pollutants? NO, Class 1 Ozone Depletors? NO, Class 2 Ozone Depletors? NO Clean Water Act: Hazardous Substance? NO, Priority Pollutant? NO, Toxic Pollutant? NO Chemical Weapons Convention: None of the components in this product are on this list. Drug Enforcement Agency (DEA) CDTA: None of the components in this product are on this list. Environmental Protection Agency: Hypochlorous acid in this product solution is an EPA-registered biocide, chemical code 129054. OSHA: None of the components in this product are considered Highly Hazardous by OSHA. 17. DISCLAIMER Data presented in this document are provided in good faith and believed to be correct as of this writing. Briotech Inc. makes no representations as to the completeness or accuracy of the information presented within this document and stipulate that the information contained within is provided upon the condition that the persons receiving this MSDS will make their own determinations as to its suitability for their intended applications of the product. Since the product is within the exclusive control of the user, it is the user’s obligation to determine the conditions of safe use of this product. These conditions should be in compliance with all Federal, State and Local Regulations concerning the Product. It must be recognized that the physical and chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from reactions with other chemicals. The data presented in this document is based on our present knowledge and shall not constitute a guarantee or warranty for any specific product features and shall not establish a legally valid contractual relationship. There are no representations or warranties, either expressed or implied, of merchantability, of fitness for a given application provided herein with respect to the product or the data presented in this record. END OF DOCUMENT
Normalized Intensity (arb.u)
50
FDA FACILITY REG #3012261723 | EPA #93108
BRIOTECH, ITS LOGOS, LANGUAGE & IMAGES ARE TRADEMARKS & COPYRIGHT PROPERTY OF BRIOTECH, INC. & ITS AFFILIATES. © 2013-2018

MATERIAL SAFETY DATA SHEET

Date Issued: 04.01.2017   Revision: 2.0 By: BRIOTECH

BRIOTECH HOCL

BRIOTECH, INC. assumes no legal responsibility for application or reliance on the data provided in this document. The information is provided in good faith and without warranty. All risks are assumed by the product user. 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name: BRIOTECH HOCL Synonym: HOCl, Cl HO, Hypochlorous Acid, Electrolyzed Water, Electro-chlorinated Water, Dilute Aqueous Saline Solution Company Information:     Comment: To the best of our knowledge, this Material Safety Data Sheet is in compliance with US OSHA 29 CFR 1910.1200, 91/155/EEC as well as the Canadian Hazardous Products Act. 2. COMPOSITION OF BRIOTECH HOCL Electro-chlorinated Water: a. CAS Registry – Chemical Abstract Service Registration Number b. EINECS – European Inventory of Existing Chemical Substances c. RTECS – Registry of Toxic Effects of Chemical Substances d. TSCA – Toxic Substance Control Act 3. HAZARDOUS IDENTIFICATION This product does not contain hazardous materials as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200; or as defined under SARA 311 and 312. Physical Appearance: Colorless, clear liquid Cautions: In sensitive individuals, may cause eye and skin irritations; may cause digestive tract irritation, nausea, vomiting and/or diarrhea. Risk by accidental inhalation are not known but considered minimal. 4. PURITY OF COMPOSITION: Using Molecular Analysis Raman Spectroscopy Presenting a single prominent point indicating no other species other than HOCl (UW Physical Sciences Laboratory 2015/2017).
BRIOTECH, INC. 19816 – 141st Place NE Woodinville, WA 98072 TEL:  425.488.4300          TOLL FREE:  888.900.6063 WEB:  www.briotechusa.com   |   http://briotechinternational.comEMAIL:  info@briotechusa.com          FAX:  425.398.9992
Component Water         Sodium Chloride    Hypochlorous Acid
Wt % 99.08 % 0.90 % 0.02 %
aCAS Registry 7732-18-5 8028-77-1 7790-92-3
bEINECS 215-185-5 231-598-3 232-232-5
cRETECS ZC0110000 VZ4725000 NH3470000
dTSCA TSCA 8(b) TSCA 8(b) TSCA 8(b)
Wavenumbers (cm    )
-1
Normalized Intensity (arb.u)
5. STABILITY OF COMPOSITION:  450 day half life 6. FIRST AID MEASURES This product is not known to cause any irritations by contact to the eyes, skin, through inhalation or ingestion; however, individuals may respond differently to various applications and in the interest of safety we elaborate on the previously mentioned cautions. This product is not for consumption; in an event of accidental exposure or overexposure through: Eye Contact: Safe for eyes; If irritation develops, check for and remove contact lenses if present. If irritation persists, rinse with cool, clean water. Skin Contact: Safe for skin contact; If irritation develops, wash with clean cool water. Ingestion: Safe for ingestion; however, as a saline product, can cause nausea if swallowed. If irritation develops, drink 2 to 4 cups of milk or water. Note that this is a topical product and not intended for consumption. Inhalation: Safe for inhalation: If irritation develops, remove from exposure to Briotech HOCl and into fresh air. 7. FIRE FIGHTING MEASURES This aqueous medium is not considered a fire hazard (non- flammable material). 8. ACCIDENTAL RELEASE MEASURES Minor spills may be mopped up and discarded in waste or sink. Major spills (industrial) should be cleaned up as you would for  salt water. No personal protective gear required; e.g., protective gloves, goggles, face shield, apron. The material is not hazardous and turns to normalized saline upon contact. 9. HANDLING AND STORAGE Industrial Handling: Keep containers tightly closed and away from UV.  Normal Handling: No special handling required. Storage: Store in a cool dry place away from direct sunlight and heat. Do not freeze. Minimum Temperature: 4°C Maximum Temperature: 70°C Optimum Temperature: 20°C to 25°C 10. PHYSICAL AND CHEMICAL PROPERTIES Physical State and Appearance: Clear, colorless liquid Odor: Very dilute chlorine or bleach Molecular Weight (g/mol): As a whole; N/A Chemistry: Individual Components:   Water – 18.02;   Sodium Chloride – 58.44;   Hypochlorous Acid – 52.46 pH: Produced between 3.9 and 6.5 Vapor Pressure (mm Hg): 760 Boiling Point: 101°C Freezing Point: May begin to freeze at -0.1°C with concomitant precipitation of sodium chloride Solubility: Water (complete) Specific Density (g/mL at 20 oC): 1.0 % Volatiles: None Flash Point: N/A 11. STABILITY AND REACTIVITY Conditions to Avoid: The material is considered safe under normal storage and handling conditions. Avoid high temperature, heat, sparks and flames. The medium is non- flammable. Chemical Stability: This product is uniquely stable and safe in closed containers stored cool and dark (away from direct sunlight and sources of heat). Hazardous Polymerization: Has not been reported and highly unlikely to occur. Hazardous Decomposition Products: Low concentrations of chlorine may evolve if heated. Incompatibilities: Ammonia, ammonium salts, reducing agents, reactive metals, iron and steel, aziridine, methanol, formic acid. 12. TOXICOLOGICAL INFORMATION No known hazards in normal use or exposure. Acute Dose Effects— Eyes: Mild irritation Inhalation LC     : No data available for solution; decomposition as chlorine 293 ppm in 1 hour (rat); 137 ppm in 1 hour (mouse); note solutions are very dilute and the total amounts shown exceed that per liter of solution (rat). Dermal / Skin: Removes natural oils from skin causing dryness, prolonged exposure may result in irritation LD50 > 5000 mg/kg. Oral: LD50 3000 mg/kg (rat); 4000 mg/kg (mouse). Sensitization: N/A Carcinogenicity As Listed by IARC: None As Listed by NTP: None As Listed by OSHA: None As Listed by ACGIH: None As Listed by NIOSH: None Mutagenicity: N/A Reproductive Effects: N/A Teratogenic Effects: N/A 13. ECOLOGICAL INFORMATION Environmental Impact: This product is not expected to bio- accumulate. When released into the air or water, its projected half-life is estimated to be <1 to 10 days. Accidental spills in aquatic environments are to be avoided due to salt content; expect immediate oxidative dilution on occurrence. 14. DISPOSAL CONSIDERATION As a waste, this material in its raw form is not considered Hazardous Waste under RCA (29 CFR 261). Waste should be appropriately diluted and pH balanced to local water management standards with water and flushed to drain as local, state and federal ordinances allow and following proper waste stream management policies of the same and for the company. 15. TRANSPORTATION INFORMATION Product Label: BRIOTECH HOCL: Hypochlorous Acid/ Dilute Aqueous Saline Solution D.O.T. Shipping Name: Water, Saline Water Technical Shipping Name: Oxidized Water D.O.T. Hazard Class: None UN Number: None D.O.T. Label: None D.O.T. Placard: None Bulk Class: N/A Package Class: 70, PG III Canadian Transport and European Transport Information not available or known. 16. REGULATORY INFORMATION TSCA Chemical Inventory: All of the components in this product are listed on the TSCA Inventory. TSCA Sec 4 Chemical Test Rule: None of the components in this product are under a Chemical Test Rule. TSCA Sec 8(d): None of the components in this product are on the Health and Safety Reporting List. TSCA Sec 12(b) Notices of Export: None of the components in this product are on this list. TSCA Significant New Use Rule (SNUR): None of the components in this product are on this list. SARA Sec 302 (EHS) TPQ: None of the components in this product have a TPQ. SARA Sec 302 (EHS) RQ: None of the components in this product have a RQ. SARA Sec 311/312: NO; Chronic – NO; Fire – NO; Release of Pressure – NO; Reactivity – NO SARA 313 List: None of the product components are reportable under Section 313 Title III and 40 CFR Part 372. CERCLA Hazardous Substances and Corresponding RQs:  N/A RCRA: None of the components in this product are on this list. Clean Air Act: Hazardous Air Pollutants? NO, Class 1 Ozone Depletors? NO, Class 2 Ozone Depletors? NO Clean Water Act: Hazardous Substance? NO, Priority Pollutant? NO, Toxic Pollutant? NO Chemical Weapons Convention: None of the components in this product are on this list. Drug Enforcement Agency (DEA) CDTA: None of the components in this product are on this list. Environmental Protection Agency: Hypochlorous acid in this product solution is an EPA-registered biocide, chemical code 129054. OSHA: None of the components in this product are considered Highly Hazardous by OSHA. 17. DISCLAIMER Data presented in this document are provided in good faith and believed to be correct as of this writing. Briotech Inc. makes no representations as to the completeness or accuracy of the information presented within this document and stipulate that the information contained within is provided upon the condition that the persons receiving this MSDS will make their own determinations as to its suitability for their intended applications of the product. Since the product is within the exclusive control of the user, it is the user’s obligation to determine the conditions of safe use of this product. These conditions should be in compliance with all Federal, State and Local Regulations concerning the Product. It must be recognized that the physical and chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from reactions with other chemicals. The data presented in this document is based on our present knowledge and shall not constitute a guarantee or warranty for any specific product features and shall not establish a legally valid contractual relationship. There are no representations or warranties, either expressed or implied, of merchantability, of fitness for a given application provided herein with respect to the product or the data presented in this record. END OF DOCUMENT
50
BRIOTECH, ITS LOGOS, LANGUAGE, AND IMAGES ARE TRADEMARKS AND/OR THE COPYRIGHT PROPERTY OF BRIOTECH, INC. AND/OR ITS AFFILIATES. © 2013-2018
FDA FACILITY REG #3012261723 | EPA #93108